Meribary MonsalveJesús ContrerasE. LaredoFrancisco López‐Carrasquero2026-03-222026-03-22201010.3144/expresspolymlett.2010.54https://doi.org/10.3144/expresspolymlett.2010.54https://andeanlibrary.org/handle/123456789/45478Citaciones: 21Copolymers of racemic -butyrolactone ((R,S)-BL) and -caprolactone (CL), were synthesized by ring-opening polymerization initiated by sodium hydride (NaH). The initiator exhibited a satisfactory catalytic activity, producing copolymers whose yields are greatly influenced by the feed monomer ratio, CL/BL. All polymers obtained were characterized by nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and wide angle X-rays scattering, WAXS. The molar composition of copolyesters determined by 1 H-NMR spectra, showed that the incorporation of CL is favoured over the incorporation of (R,S)-BL. Gel permeation chromatography and 13 C-NMR spectra indicated that CL/BL copolymers had block sequence distribution. The TGA analysis of copolymers showed that these copolymers are stable up to temperatures near 200C, followed by a decomposition process in two steps; the first one is attributed to the (R,S)-BL block degradation and the second to the remaining PCL block. The crystallization process of these copolymers was studied by DSC and WAXS showing that the amorphous (R,S)-BL segments chains did not affect the crystallinity of the PCL blocks.enCaprolactoneSodium hydrideCopolymerHydrideMaterials sciencePolymer chemistryRing-opening polymerizationRing (chemistry)article