Synthesis, characterization and olefin hydroformylation reactions of mer-[Mo(CO)3(p-C5H4N-CN)3]

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dc.contributor.authorTrino Suárez
dc.contributor.authorBernardo Fontal
dc.contributor.authorMaría Parra
dc.contributor.authorMarisela Reyes
dc.contributor.authorFernándo Bellandi
dc.contributor.authorJuan Carlos Dı́az
dc.contributor.authorPedro Cancines
dc.contributor.authorYuraima Fonseca
dc.coverage.spatialBolivia
dc.date.accessioned2026-03-22T15:46:00Z
dc.date.available2026-03-22T15:46:00Z
dc.date.issued2010
dc.descriptionCitaciones: 4
dc.description.abstractMer-[Mo(CO)3(p-C5H4N-CN)3] was prepared by UV-irradiation of a THF solution of Mo(CO)6 and para-cyanopyridine under heating. The complex was characterized by FT-IR, MS, 1H and 13C NMR and showed catalytic activity for olefin hydroformylation (1-hexene, cyclohexene and 2,3-dimethyl-2-butene as model olefins; 600 psi synthesis gas (pCO/pH2 = 1); 100 °C; 24 h; toluene). An examination of the complex catalyzed hydroformylation of a real naphtha cut (El Palito refinery, Venezuela), under the same conditions, also showed activity in the conversion to oxygenated products.
dc.identifier.doi10.1007/s11243-009-9326-5
dc.identifier.urihttps://doi.org/10.1007/s11243-009-9326-5
dc.identifier.urihttps://andeanlibrary.org/handle/123456789/54284
dc.language.isoen
dc.publisherSpringer Science+Business Media
dc.relation.ispartofTransition Metal Chemistry
dc.sourceUniversidad de Los Andes
dc.subjectHydroformylation
dc.subjectOlefin fiber
dc.subjectChemistry
dc.subjectToluene
dc.subjectCatalysis
dc.subjectOrganometallic chemistry
dc.subjectCyclohexene
dc.subjectNaphtha
dc.subject1-Hexene
dc.subjectOrganic chemistry
dc.titleSynthesis, characterization and olefin hydroformylation reactions of mer-[Mo(CO)3(p-C5H4N-CN)3]
dc.typearticle

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