Synthesis, characterization and hydrogenation catalysis in biphasic medium (organic/water) of samarium (III) complex with glycine and 2,2-bipyridine ligands

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dc.contributor.authorEduardo Cardozo
dc.contributor.authorJoel E. Vielma
dc.contributor.authorBernardo Fontal
dc.contributor.authorR. Contreras
dc.contributor.authorMarisela del C. Reyes
dc.contributor.authorFernándo Bellandi
dc.contributor.authorYuraima Fonseca
dc.contributor.authorVictoria Romero
dc.coverage.spatialBolivia
dc.date.accessioned2026-03-22T16:13:03Z
dc.date.available2026-03-22T16:13:03Z
dc.date.issued2015
dc.descriptionCitaciones: 1
dc.description.abstractSm(bipy)(glycine)3 [bipy = 2,2-bipyridine] was synthesized by classic, microwave and mechanical methods. UV-Vis reveals a strong signal near 190 nm corresponding to a high energy Sm-O bond and f→f transitions. FT-IR spectra show a band between 490 - 450 cm-1 indicative of a Sm-O bond. TGA-DTA and MS analytical analysis, confirm the structural proposals. The samarium (III) complex was tested in 1-hexene hydrogenation, in biphasic media (cyclohexane/water) and the reaction parameters were optimized (time, temperature, substrate/catalyst ratio and H2 pressure). Catalystshowed 37.5 % conversion.
dc.identifier.doi10.53766/avanquim/2015.10.01
dc.identifier.urihttps://doi.org/10.53766/avanquim/2015.10.01
dc.identifier.urihttps://andeanlibrary.org/handle/123456789/56928
dc.language.isoen
dc.publisherUniversidad de Los Andes
dc.relation.ispartofAvances en Química
dc.sourceUniversity of the Andes
dc.subjectSamarium
dc.subjectGlycine
dc.subjectCatalysis
dc.subjectChemistry
dc.subjectBipyridine
dc.subject2,2'-Bipyridine
dc.subjectCharacterization (materials science)
dc.subjectOrganic chemistry
dc.subjectPolymer chemistry
dc.subjectCombinatorial chemistry
dc.titleSynthesis, characterization and hydrogenation catalysis in biphasic medium (organic/water) of samarium (III) complex with glycine and 2,2-bipyridine ligands
dc.typearticle

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