New Camphor-Derived Selenonium Ylides: Enantioselective Synthesis of Chiral Epoxides

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dc.contributor.authorXinliang Li
dc.contributor.authorYi Wang
dc.contributor.authorZhi‐Zhen Huang
dc.coverage.spatialBolivia
dc.date.accessioned2026-03-22T14:59:58Z
dc.date.available2026-03-22T14:59:58Z
dc.date.issued2005
dc.descriptionCitaciones: 16
dc.description.abstractOptically pure selenonium salts 3 as the precursors of two new chiral selenonium ylides 4 can be synthesized stereoselectively from natural d-camphor in good yields. It is found that the reaction of the selenonium salt 3b, an aldehyde, and potassium tert-butoxide can take place smoothly in ‘one-pot’ via the formation of selenonium ylide 4b, to give chiral trans-diaryl epoxides 5 in good yields with good diastereoselectivities and enantioselectivities.
dc.identifier.doi10.1071/ch05157
dc.identifier.urihttps://doi.org/10.1071/ch05157
dc.identifier.urihttps://andeanlibrary.org/handle/123456789/49792
dc.language.isoen
dc.publisherCSIRO Publishing
dc.relation.ispartofAustralian Journal of Chemistry
dc.sourceNanjing University
dc.subjectChemistry
dc.subjectYlide
dc.subjectCamphor
dc.subjectBiocatalysis
dc.subjectEnantioselective synthesis
dc.subjectAldehyde
dc.subjectGreen chemistry
dc.subjectOrganic chemistry
dc.subjectIonic liquid
dc.subjectSalt (chemistry)
dc.titleNew Camphor-Derived Selenonium Ylides: Enantioselective Synthesis of Chiral Epoxides
dc.typearticle

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