Adsorption of cadmium by a high-capacity adsorbent composed of silicate-titanate nanotubes embedded in hydrogel chitosan beads

Abstract

In this study, we developed a nanoparticle-based mesoporous composite that consisted of silicate-titanate nanotubes (STNTs) supported in hydrogel chitosan beads (STNTs-Ch beads) and was studied for Cd²⁺ adsorption. By using Fourier-transform infrared spectroscopy, transmission and scanning electron microscopy coupled to an energy-dispersive X-ray spectrometer, we could determine that the hollow STNTs were highly dispersed in the walls of the hollow beads. The dispersion was attributed to the effect of pH when the composite was prepared and we observed a non-interaction between STNTs and chitosan. The adsorption studies of Cd²⁺ showed that the kinetic rate (<i>k</i> ₂) increased 3-fold and that the diffusion rate (<i>K</i> _d) increased 2-fold after the embedment. Moreover, the maximum capacity of adsorption of STNTs-Ch beads was 2.3 times higher than that of STNTs alone. The treatment of a synthetic Cd²⁺ solution and a real leachate in continuous mode showed two phases in which it was observed higher removed fractions of transition metal ions (Cd²⁺, Co²⁺, Ni²⁺, Zn²⁺ and Cu²⁺) and the post-transition metal ion Pb²⁺, in comparison to the removed fractions of alkali and alkali-earth metal ions (Ca²⁺, K⁺, Mg²⁺). The composite was successfully reused four times when adsorbing Cd²⁺, saving three times the needed amounts of TiO₂, SiO₂ and chitosan for the production of the material. This composite was produced in a simple way and shows the potential for wastewater treatment.