Solvent-Induced Chirality in the Hydroboration of Ketones

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dc.contributor.authorChristoph Baldauf
dc.contributor.authorNina Dickerhof
dc.contributor.authorStefan H. Hüttenhain
dc.contributor.authorStefanie Kern
dc.contributor.authorNancy Krummrich
dc.contributor.authorFriedrich Kruse
dc.contributor.authorJanine May
dc.contributor.authorMelanie Meister
dc.contributor.authorKristina Müller
dc.contributor.authorSabine Rauer
dc.coverage.spatialBolivia
dc.date.accessioned2026-03-22T16:43:13Z
dc.date.available2026-03-22T16:43:13Z
dc.date.issued2008
dc.descriptionCitaciones: 1
dc.description.abstractThe influence of the systematic variation of chiral solvents and of diverse Lewis acids on the asymmetric induction of the hydroboration of acetophenone has been studied. None of the solvents used could surpass lactic acid methyl ester, and for the Lewis acids, ZnCl2 and ZnI2 showed positive effects on the enantiomeric excess (ee) and the conversion. Also, the effect of the substrate structure was investigated by comparing the conversion and ee of eight different ketones. Apparently, the achievable asymmetric induction was higher with aromatic ketones.
dc.identifier.doi10.1071/ch08093
dc.identifier.urihttps://doi.org/10.1071/ch08093
dc.identifier.urihttps://andeanlibrary.org/handle/123456789/59905
dc.language.isoen
dc.publisherCSIRO Publishing
dc.relation.ispartofAustralian Journal of Chemistry
dc.sourceDarmstadt University of Applied Sciences
dc.subjectHydroboration
dc.subjectChemistry
dc.subjectBiocatalysis
dc.subjectAcetophenone
dc.subjectChirality (physics)
dc.subjectAsymmetric induction
dc.subjectLewis acids and bases
dc.subjectGreen chemistry
dc.subjectEnantiomer
dc.subjectEnantiomeric excess
dc.titleSolvent-Induced Chirality in the Hydroboration of Ketones
dc.typearticle

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